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Persulfates: Potassium Peroxymonosulfate, Ammonium Persulfate, Sodium Persulfate, Potassium Persulfate, Peroxydisulfuric Acid, P

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Persulfates: Potassium Peroxymonosulfate, Ammonium Persulfate, Sodium Persulfate, Potassium Persulfate, Peroxydisulfuric Acid, P

Synopsis

Chapters: Potassium Peroxymonosulfate, Ammonium Persulfate, Sodium Persulfate, Potassium Persulfate, Peroxydisulfuric Acid, Peroxomonosulfate. Source: Wikipedia. Pages: 22. Not illustrated. Free updates online. Purchase includes a free trial membership in the publisher's book club where you can select from more than a million books without charge. Excerpt: Potassium peroxymonosulfate (also known as MPS, potassium monopersulfate, and the trade names Caroat and Oxone) is widely used as an oxidizing agent. It is the potassium salt of peroxymonosulfuric acid. The potassium salt is marketed by two companies: Evonik (formerly Degussa) under the tradename Caroat and DuPont under the tradename Oxone, tradenames which are now part of standard chemistry vocabulary. It is a component of a triple salt with the formula 2KHSO5 KHSO4 K2SO4. The standard electrode potential for this compound is 1.44 V with a half reaction generating the hydrogen sulfate. HSO4 + H2O HSO5 + 2 H + 2 e Oxone is a versatile oxidant. It oxidizes aldehydes to carboxylic acids; in the presence of alcoholic solvents, the esters may be obtained. Internal alkenes may be cleaved to two carboxylic acids, while terminal alkenes may be epoxidized. Thioethers give sulfones, tertiary amines give amine oxides, and phosphines give phosphine oxides. Illustrative of the oxidation power of this salt is the conversion of an acridine derivative to the corresponding acridine-N-oxide. It will also oxidize a thioether to a sulfone with 2 equivalents. With one equivalent the reaction converting sulfide to sulfoxide is much faster than that of sulfoxide to sulfone, so the reaction can conveniently be stopped at that stage if so desired. Applications Technical ...More: http: //booksllc.net/?id=230164

Product Details

ISBN:
9781158454853
Category:
Books
Format:
Paperback, softback
Publication Date:
2010-09-15
Publisher:
Books LLC
Country of origin:
USA
Pages:
24
Weight:
50g

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