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Two Studies in Gas-Phase Ion Spectroscopy

Two Studies in Gas-Phase Ion Spectroscopy

Vacuum-Ultraviolet Negative Photoion Spectroscopy and Ion-Molecule Reaction Kinetics

by Matthew J. Simpson
Paperback
Publication Date: 28/11/2013
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In this thesis Matthew Simpson reportstwo areas of work in gas ion spectroscopy, each investigation in itself worthy of a PhD. The first study uses tunable vacuum-ultraviolet radiation from a synchrotron to identify negative ions from twenty four photoexcited polyatomic molecules in the gas phase. From these experiments, Matthew collects a vast amount of data and summarises and reviews ion-pair formation from polyatomic molecules. The second study is on selected ion flow tube mass spectrometry. Matthew investigates the reactions of cations and anions with ethene, monofluoroethene, 1,1-difluoroethene and tetrafluoroethene. In this study Matthew tries to explain why certain products are formed preferentially over other products at a microscopic level of understanding. The data recorded in this thesis form the most comprehensive collection of information about anion formation and are the basis of a review and numerous articles in specialist journals.
ISBN:
9783642271274
9783642271274
Category:
Spectrum analysis
Format:
Paperback
Publication Date:
28-11-2013
Language:
English
Publisher:
Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Country of origin:
Germany
Pages:
162
Dimensions (mm):
235x155x10mm
Weight:
0.28kg

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