This book constitutes the thoroughly refereed post-proceedings of the Second European Workshop on 3D Structure from Multiple Images of Large-Scale Environments, SMILE 2000, held in Dublin, Ireland in July 2000. The 12 revised full papers presented together with one invited paper and transcriptions of the panels following the three sessions were carefully reviewed and revised for inclusion in the book. The papers are organized in topical sections on computation and algorithms, visual scene representations, and extended environments.